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    Electrocyclic ring opening reaction of cyclopropane system to give rearranged allylic products

    Electrocyclic ring opening reaction of cyclopropane system to give rearranged allylic products

    Cyclopropane ring opening in thermal conditions occurs via disrotatory manner to give rearranged allylic carbocation. Solvolysis of cyclopropane and 5-3 fused ring systems proceeds with considerably different rates exclusively through anchimeric assistance mechansim.